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81.
In 2001, J.-M. Le Bars disproved the zero-one law (that says that every sentence from a certain logic is either true asymptotically almost surely (a.a.s.), or false a.a.s.) for existential monadic second order sentences (EMSO) on undirected graphs. He proved that there exists an EMSO sentence ? such that does not converge as (here, the probability distribution is uniform over the set of all graphs on the labeled set of vertices ). In the same paper, he conjectured that, for EMSO sentences with 2 first order variables, the zero-one law holds. In this paper, we disprove this conjecture. 相似文献
82.
Bilender P. Allahverdiev 《Mathematical Methods in the Applied Sciences》2019,42(1):229-236
In this study, maximal dissipative second‐order dynamic operators on semi‐infinite time scale are studied in the Hilbert space , that the extensions of a minimal symmetric operator in limit‐point case. We construct a self‐adjoint dilation of the dissipative operator together with its incoming and outgoing spectral representations so that we can determine the scattering function of the dilation as stated in the scheme of Lax‐Phillips. Moreover, we construct a functional model of the dissipative operator and identify its characteristic function in terms of the Weyl‐Titchmarsh function of a self‐adjoint second‐order dynamic operator. Finally, we prove the theorems on completeness of the system of root functions of the dissipative and accumulative dynamic operators. 相似文献
83.
Claudianor O. Alves Daniel C. de Morais Filho Giovany M. Figueiredo 《Mathematical Methods in the Applied Sciences》2019,42(14):4862-4875
In this work, we prove the existence of positive solution for the following class of problems where λ>0 and is a potential satisfying some conditions. Using the variational method developed by Szulkin for functionals, which are the sum of a C1 functional with a convex lower semicontinuous functional, we prove that for each large enough λ>0, there exists a positive solution for the problem, and that, as λ→+∞, such solutions converge to a positive solution of the limit problem defined on the domain Ω=int(V?1({0})). 相似文献
84.
Experimental data from vented explosion tests using stoichiometric methane–air and 18% hydrogen–air mixtures in a 63.7 m3 chamber with a 2.7 or 5.4 m2 vent are presented. Results from experiments conducted using stoichiometric propane–air in 2.42 m3 vessel with a 0.26 m2 vent are also reported. The tests were focused on the effect of fuel, enclosure size, ignition location, vent size, and obstacles on the pressure development of a propagating flame in a vented enclosure. The dependence of the maximum pressure generated on the experimental parameters was analyzed. It was found that the pressure maxima may be caused by pressure transients controlled by the interplay of the maximum-flame area, the burning velocity, and the overpressure generated by an external explosion. A simple model was proposed to estimate the maximum pressure for each of the main pressure transients. The model was found to agree with the experimental data within the experimental uncertainty. 相似文献
85.
《Analytical letters》2012,45(5):441-450
Abstract A microcell has been constructed for stripping analysis in solution volumes as low as 5 μl, employing a glassy carbon or mercury-plated glassy carbon working electrodes and a three electrode system. Using normal d.c. stripping techniques, as little as 100 picograms of mercury and 10 picograms of lead can be determined. With the more sensitive second harmonic a.c. voltammetric technique, this limit is lowered to 10 picograms of mercury and 1 picogram of lead. 相似文献
86.
S. Yakubovich 《Integral Transforms and Special Functions》2018,29(3):171-188
New index transforms with Weber-type kernels, consisting of products of Bessel functions of the first and second kind, are investigated. Mapping properties and inversion formulas are established for these transforms in Lebesgue spaces. The results are applied to solve a boundary value problem on the wedge for a fourth-order partial differential equation. 相似文献
87.
Anupam Bhim Prof. Jean-Pascal Sutter Prof. Jagannatha Gopalakrishnan Prof. Srinivasan Natarajan 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(6):1995-2008
The stuffed tridymite structure Ba(Zn/Co)1−xSi1−xM2xO4 (M=Al3+ and Fe3+) is explored for the possible multiferroic behavior and to develop new inorganic colored materials. The compounds were synthesized by employing conventional solid-state chemistry methods in the temperature range 1100–1175 °C for 24 h. The powder X-ray diffraction (PXRD) and Rietveld refinement studies indicate that the compounds stabilize in the P63 space group (no. 173). The refinement results were also rationalized by employing Raman spectroscopic studies. The compounds were found to be second harmonic generation (SHG) active and show weak ferroelectric behavior. The co-substitution of Co2+ and Fe3+ in the structure gives rise to a weak ferromagnetic behavior to the compound, BaCo0.75Si0.75Fe0.5O4, making it a multiferroic material. The optical studies on the prepared compounds exhibited blue color (Co2+ in Td geometry), purple color (Ni2+ in Td geometry), and simultaneous substitution of Co2+ and Fe3+ gives rise to blue-green color owing to metal-to-metal charge transfer (MMCT) effect. 相似文献
88.
Solution properties,unperturbed dimensions,and chain flexibility of poly(1‐adamantyl acrylate) 下载免费PDF全文
Wei Lu Panchao Yin Masashi Osa Weiyu Wang Nam‐Goo Kang Kunlun Hong Jimmy W. Mays 《Journal of Polymer Science.Polymer Physics》2017,55(20):1526-1531
Poly(1‐adamantyl acrylate) (PAdA) exhibits much higher glass transition and degradation temperatures than other polyacrylates. However, the quantitative evaluation of the stiffness of this polymer chain has not been reported previously. In this study, the dilute solution properties and conformational characteristics of PAdA were evaluated using viscometry and scattering techniques. The unperturbed dimensions of this polymer were evaluated using the Burchard–Stockmayer–Fixman extrapolation and the touched‐bead wormlike chain model. The PAdA chain has a comparable persistence length, diameter per bead and characteristic ratio to poly(methyl methacrylate) and polystyrene. All these results indicate that PAdA is less flexible than common polyacrylates. In addition, the second virial coefficients (A2) of PAdA in different solvents obtained by static light scattering were compared. Among the solvents investigated, tetrahydrofuran is a moderate solvent. Radius of gyration of a polymer sample in the various solvents ranged from 16.8 to 30.3 nm. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2017 , 55, 1526–1531 相似文献
89.
The hydrogen bonding pattern in complexes of the type [M2+(H2O)6](dmax)2 (M = Mn, Ni, Co, Zn, Cd, Hdmax = 1,3-dimethyl-8-azaxanthine), [M2+(H2O)4(py)2](dmax)2 (M = Mn, Co, Zn, Cd, py = pyridine) and [M2+(dmax)2(H2O)2(py)2]·2H2O (M = Ni, Cu) were studied by ab initio (MP2/LANL2DZ//B3LYP/LANL2DZ) and density functional theory methods (B3LYP/LANL2DZ, B3LYP/6-31G∗∗ and B3PW91/6-31G∗∗). The investigation includes a variety of theoretical analyses, which include interaction energy, many body analyses, electron density analysis, topological analysis, Mulliken atomic charges, natural atomic charges and harmonic vibrational analysis. The geometrical parameters and vibrational frequencies of dmax (the mono anion of 1,3-dimethyl-8-azaxanthine), [M2+(H2O)6] (M = Mn, Ni, Co, Zn, Cd), [M2+(H2O)4·(py)2] (M = Mn, Co, Zn, Cd) and the complexes, calculated by the theoretical methods, were compared with the recent X-ray crystallographic results and it was observed that the results are found to agree well with the crystallographic results. The present calculations provide an important physicochemical insight into metal cations with 1,3-dimethyl-8-azaxanthine. The results also reveal the active role of coordinated water molecules in modulating the binding of the cation through a specific network of hydrogen bonds. The topology of the motifs generated by these hydrogen bonds has been characterized, adapting to the second coordination sphere concepts usually applied to the first (monodentate, chelate, and bridge) coordination sphere. The optimized structures of the Cd2+, Zn2+ and Cu2+ complexes further interact among themselves in a less tight fashion to generate three dimensional structures (a tape-like hydrogen bond network). Finally these tape-like hydrogen bond network were optimized using the B3LYP/LANL2DZ basis set. 相似文献
90.
Vladan Mlinar 《Annalen der Physik》2015,527(3-4):187-204
In the light of recent developments in computer technology, a promising and efficient way to design a material with a desired property would be to solve the inverse problem: use a physical property to predict structure. Here, we discuss the basic idea and mathematical foundation of the inverse approach, and proposed strategies for its utilization in the design of materials over nano‐ to macro‐scales. At the nano‐scale, analyzed strategies include scanning of a high‐dimensional space of chemical compounds for those compounds that have a targeted property, and identification of correlations in large databases of materials. However, unlike utilization of inverse approach at nano‐scale where full structural information ‐ atoms and their positions‐ is linked to targeted properties, at the meso‐ and macro‐scale, only partial structural information, manifested via structural motifs or representative volume elements, is available. We discuss the role of partial structural information in the inverse approach to the design of materials at those scales. Risks and limitations of the inverse approach are analyzed and dependence of the approach on factors such as structure parametrization, approximations in theoretical models, and feedback from structural characterization, is addressed.